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. In brief, all FTIR experiments were performed on a Perkin-Elmer Spectrum 2000 spectrometer (Wellesley, MA) equipped with a dTGS detector
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. At temperatures above 70°C, all the bands except those from the β-turn (1668 and 1674 cm^sup -1^) possessed similar melting curves, which indicated that a major conformational change occurred in this temperature range
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. Departures from Flory's random-coil model are based on field-theoretic approaches (39-42) that explicitly account for the effects of correlations in a self-repelling chain
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. ProcedurePermission from the human subjects review board was granted to conduct the current study
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